The crystal structure and microstructure of as-prepared and annealed Ni0.9Zn0.1O were refined at room temperature in both the Fm (3) over barm and R (3) over barm space groups. It is shown that below the Neel point (458 K), where magnetic ordering triggers the presence of a trigonal strain, the common usage of a higher-symmetry non-admissible space group for crystal structure and microstructure analysis via the Rietveld method may result in both an incorrect structure description and incorrect microstructure ...
Kremenović Aleksandar, Antić Bratislav, Vučinić-Vasić Milica, Colomban Philippe, Jovalekić Čedomir, Bibić Nataša, Kahlenberg Volker, Leoni Matteo. "Temperature induced evolution of nanostructured Ni0.9Zn0.1O" in Journal of Applied Crystallography no. 43, Denmark: Blackwell Munksgaard (2010). https://doi.org/10.1107/S0021889810019163 M21
