Water in the Alluaudite Type-Compounds: Synthesis, Crystal Structure and Magnetic Properties of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H,□)0.5(H2O,H3O)0.5]2x+

Објеката

Тип

Рад у часопису

Верзија рада

објављена верзија

Језик

енглески

Креатор

Tamara Đorđević, Ljiljana Karanović, Marko Jagodič, Zvonko Jagličić

Извор

Minerals

Издавач

MDPI AG

Датум издавања

2021

Сажетак

In this study, a new cobalt arsenate belonging to the alluaudite supergroup compounds with the general formula of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H, )0.5(H2O,H3O)0.5]2x+ (denoted as CoAsAllu) was synthesized under hydrothermal conditions. Its crystal structure was determined by a room-temperature single-crystal X-ray diffraction analysis: space group C2/c, a = 11.6978(8), b = 12.5713(7), c = 6.7705(5) Å, b = 113.255(5)◦, V = 914.76(11) Å3, Z = 2 for As6H8Co6O25. It represents a new member of alluaudite-like protonated arsenates and the first alluaudite-like phase showing both protonation of the tetrahedral site and presence of the H2O molecules in the channels. In the asymmetric unit of CoAsAllu, one of the two Co, one of the two As and one of the seven O atoms lie at 4e special positions (site symmetry 2). The crystal structure consists of the infinite edge-shared CoO6 octahedra chains, running parallel to the [101] direction. The curved chains are interconnected by [(As1O4)0.5(H2As1O4)0.5]2− and [HAs2O4]2− tetrahedra forming a heteropolyhedral 3D open framework with two types of parallel channels. Both channels run along the c-axis and are located at the positions (1/2, 0, z) and (0, 0, z), respectively. The H2 and H4 hydrogen atoms of O2H2 and O4H4 hydroxyl groups are situated in channel 1, while the uncoordinated water molecule H2O7 at half-occupied 4e special positions and hydrogen atoms of O6H6 hydroxyl group were found in channel 2. The results of the magnetic investigations confirm the quasi one-dimensional structure of divalent cobalt ions. They are antiferromagnetically coupled with the intrachain interaction parameter of J ≈ −8 cm−1 and interchain parameter of J’ ≈ −2 cm−1 that become effective below the Néel temperature of 3.4 K.

том

11

Број

12

број страница

14

doi

10.3390/min11121372

issn

2075-163X

Subject

супергрупа алуаудита, арсенати прелазних метала, хидротермална синтеза, кристална структура, хидратисани хидрокси-арсенати, стехиометрија, магнетна својства

alluaudite supergroup, transition metal arsenates, hydrothermal synthesis, crystal structure, hydrated hydroxy-arsenates, stoichiometry, magnetic properties

uri

https://www.mdpi.com/2075-163X/11/12/1372/pdf

Шира категорија рада

M20

Ужа категорија рада

М22

Је дио

Министарство просвете, науке и технолошког развоја Републике Србије (пројекат бр. III45007)

Права

Отворени приступ

Лиценца

Creative Commons – Attribution 4.0 International

Формат

.pdf

ORCID

https://orcid.org/0000-0001-9534-1315

Скупови објеката

Љиљана Карановић

Radovi istraživača

Медија

minerals-11-01372.pdf

Tamara Đorđević, Ljiljana Karanović, Marko Jagodič, Zvonko Jagličić. "Water in the Alluaudite Type-Compounds: Synthesis, Crystal Structure and Magnetic Properties of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H,□)0.5(H2O,H3O)0.5]2x+" in Minerals, MDPI AG (2021). https://doi.org/10.3390/min11121372

This item was submitted on 31. децембар 2021. by [anonymous user] using the form “Рад у часопису” on the site “Радови”: http://dr.rgf.bg.ac.rs/s/repo