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2344 items
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Development and Evaluation of Three Named Entity Recognition Systems for Serbian - The Case of Personal Names
In this paper we present a rule- and lexicon-based system for the recognition of Named Entities (NE) in Serbian news paper texts that was used to prepare a gold standard annotated with personal names. It was further used to prepare training sets for four different levels of annota tion, which were further used to train two Named Entity Recognition (NER) sys tems: Stanford and spaCy. All obtained models, together with a rule- and lexicon based system were evaluated on ...... are three categories of NER systems: 1) The rule-based (RB) (Krupka and Hausman, 1998; Friburger and Maurel, 2004); 2) the Ma- chine Learning (ML) based (Finkel and Manning, 2009; Singh et al., 2010); and 3) hybrid meth- ods (Jansche and Abney, 2002). The ML-based methods can often be “black boxes”, in ...
... appli- cation that enables NER across many languages and domains),1 OpenNLP (rule-based and statisti- cal NER),2 spaCy (Honnibal and Montani, 2017) (module written in Python, used for advanced NLP)3 and many others. For Serbian, thus far a rule-based and lexicon-based NER system was developed – SRPNER (Krstev ...
... expressions (date and time, and 3) name expressions (personal, geopo- litical and organization names). The system was designed in a form of the cas- cades of Finite-State Transducers (FST) in which every transducer recognizes and tags a certain class of NEs (Friburger and Maurel, 2004; Mau- rel et al ...Branislava Šandrih, Cvetana Krstev, Ranka Stanković. "Development and Evaluation of Three Named Entity Recognition Systems for Serbian - The Case of Personal Names" in Proceedings - Natural Language Processing in a Deep Learning World, Incoma Ltd., Shoumen, Bulgaria (2019). https://doi.org/10.26615/978-954-452-056-4_122
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Investigation of nanostructured Ca0.9Er0.1MnO3 obtained by sucrose nitrate procedure
Tijana B. Vlašković, Bojana Laban, Maja Milošević, Maria Čebela, Vladimir Dodevski, Milena Rosić (2023)... Technology and Metallurgy Institute for Technology of Nuclear and Other Raw Mineral Materials PROGRAM AND THE BOOK OF ABSTRACTS Serbian Academy of Sciences and Arts, Knez Mihailova 35 Serbia, Belgrade, 18-–20. September 2023. Serbian Ceramic Society Conference ADVANCED CERAMICS AND APPLICATION ...
... Advanced Ceramics and Application : New Frontiers in Multifunctional Material Science and Processing (11 ; 2023 ; Beograd) Program ; and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian ...
... ional Material Science and Processing Serbian Ceramic Society Institute of Technical Sciences of SASA Institute for Testing of Materials Institute of Chemistry Technology and Metallurgy Institute for Technology of Nuclear and Other Raw Mineral Materials PROGRAM AND THE BOOK OF ABSTRACTS ...Tijana B. Vlašković, Bojana Laban, Maja Milošević, Maria Čebela, Vladimir Dodevski, Milena Rosić. "Investigation of nanostructured Ca0.9Er0.1MnO3 obtained by sucrose nitrate procedure" in Program ; and the Book of abstracts The Eleventh Serbian Ceramic Society Conference »Advanced Ceramics and Application« September 18-20, 2023 Serbian Academy of Sciences and Arts, Belgrade, Serbia , Belgrade : Serbian Academy of Sciences and Art Serbia (2023)
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SASA Dictionary as the Gold Standard for Good Dictionary Examples for Serbian
Ranka Stanković, Branislava Šandrih, Rada Stijović, Cvetana Krstev, Duško Vitas, Aleksandra Marković (2019)У овом раду представљамо модел за избор добрих примера за речник српског језика и развој иницијалних компоненти модела. Метода која се користи заснива се на детаљној анализи различитих лексичких и синтактичких карактеристика у корпусу састављених од примера из пет дигитализованих свезака речника САНУ. Почетни скуп функција био је инспирисан сличним приступом и за друге језике. Дистрибуција карактеристика примера из овог корпуса упоређује се са карактеристиком дистрибуције узорака реченица ексцерпираних из корпуса који садрже различите текстове. Анализа је показала да ...Српски, добри примери из речника, аутоматизација израде речника, издвајање својстава, Машинско учење... various lexical and syntactic features of the gold standard examples, classified them and compared the results with the control corpus (both gold and control corpus are presented in Section 4). The initial set of features was inspired by Kilgarriff et al. (2008) and Kosem (2017), and guided by rec ...
... ) in the sentence; and since examples should help the understanding of the definition, they must be easy to understand – which means that their syntactic structure should be simple and their lexis not too difficult and uncommon. Informativeness, typicality with naturalness, and intelligibility are ...
... while 5% had an insertion but were not shortened and 2% had both insertions and shortenings. The number of editorial examples was relatively small, and we have not used these in our test set. 2.3.5 What should a good example contain? As Atkins and Rundell (2008) point out, there is plenty of evidence ...Ranka Stanković, Branislava Šandrih, Rada Stijović, Cvetana Krstev, Duško Vitas, Aleksandra Marković. "SASA Dictionary as the Gold Standard for Good Dictionary Examples for Serbian" in Electronic lexicography in the 21st century. Proceedings of the eLex 2019 conference , Lexical Computing CZ, s.r.o. (2019)
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Production information system of the Pljevlja coal mine
Božo Kolonja, Ranka Stanković, Filip Vuković . "Production information system of the Pljevlja coal mine" in Mine Planning and Equipment Selection 2000, Routledge (2018). https://doi.org/10.1201/9780203747124-154
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The state and perspective of the natural gas sector in Serbia
The strategy of long-term energy development of Serbia identifies an increase of share of natural gas in final energy consumption as one of the main aims. Serbia has signed a strategic agreement with the Russian Federation on cooperation in the oil and gas sector, within which the project South Stream pipeline is planned to be realized. In addition, the Republic of Serbia has signed the Treaty that establishes the Energy Community and accepted the obligation to implement the Energy ...Dejan Ivezić, Marija Živković, Dušan Danilović, Aleksandar Madžarević, Miloš Tanasijević. "The state and perspective of the natural gas sector in Serbia" in Energy Sources, Part B: Economics, Planning and Policy, Taylor & Francis Group, LLC (2016). https://doi.org/http://dx.doi.org/10.1080/15567249.2013.858796
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Mesozoic carbonate rocks in Serbia used as dimension stone
Vesna Matović, Tijana Vojnović Ćalić (2016)The building industry in Serbia uses, to a great extent, imported natural stone for architectural purposes. The significance of local deposits, particularly limestones, is not adequately perceived despite the country’s abundance of these valuable resources. Therefore, this study focuses on Serbia’s Mesozoic carbonate rocks, specifically on the deposits of four selected quarries: Klisura, Skrzut, Struganik, and Tisnica. The quality and prospects of the application of these limestones has not yet been the subject of a detailed, comprehensive investigation. Therefore, ...... the base of the column and it is characterised by unsorted and densely packed bioclasts (up to ! mm), rare intraclasts and oncoids arranged in sparitic cement. Dominant red nodular limestone, allochemmicrite (Packstone and Wa- ckestone microfacies), builds the second and the third package of ...
... suitable size) and market demand (Luodes et al. 2000). Despite the fact that concrete and glass were the prin- cipal materials in architectural design during the 1970s and 1980s, in the last three decades, the demand for dimension stone has continuously increased (Siegesmund and Sneth- lage ...
... the limestones” scope of application as dimension stone—-slabs for architectural cladding and paving for exterior and interior use—with the possible effect on Serbia's building and stone industry, and eventually the export market. @ Springer V. Matović, T. V. Ćalić Study area The study ...Vesna Matović, Tijana Vojnović Ćalić. "Mesozoic carbonate rocks in Serbia used as dimension stone" in Bulletin of Engineering Geology and the Environment, Springer Science and Business Media LLC (2016). https://doi.org/10.1007/s10064-015-0722-0
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Improvement of geodatabase queries within GeolISS
Ranka Stanković (2008)... repository for digital archiving, query, retrieving, analysis and visualization of geological data. The development and implementation of the GeolISS is managed by a team from the Faculty of Mining and Geology of Belgrade University and financed by Ministry of the Environmental protection. The main ...
... field data records and measurements, the basis for classification, interpretations and modeling of geological features. Any observed property can be expressed as a text, number, picture and geometry (location). Spatial entity, which is treated as observation locations and mapped/interpreted ...
... criteria in the source and target language. A filtered TMX document is transformed into XML, TXT and HTML output files by XSLT transformations. The developed web application receives the user query, and subsequently uses the local web service WS4QE to expand the query and forward it to the Google ...Ranka Stanković. "Improvement of geodatabase queries within GeolISS" in Review of the National Center for Digitization, Beograd : Faculty of Mathematics, Belgrade (2008)
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LRMI markup of OER content within the BAEKTEL project
... physical and virtual communities, where more and more are published as Open Educational Resources (OER). Nowadays, online searches for educational materials are conducted more often than a few years ago. Although Internet searches are easy and speedy, they are not always efficient and retrieve ...
... for terminological and linguistic support, such as query expansion, information retrieval, OER indexing, and the like. OER metadata include information such as resource title, author, subject, creation date and the like, which facilitates search, but also acquisition, use and reuse of learning ...
... way to add extra semantic information and extend HTML5. [12] Microdata is specified inside itemtype and itemprop attributes added to existing HTML elements; microformat keywords are added inside class attributes and RDFa relies on rel, typeof and property attributes added to existing ...Ranka Stanković, Daniela Carlucci, Olivera Kitanović, Nikola Vulović, Bojan Zlatić. "LRMI markup of OER content within the BAEKTEL project" in The Sixth International Conference on e-Learning (eLearning-2015), September 2015, Belgrade, Serbia, Belgrade : Belgrade Metropolitan Univesity (2015)
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Arsenic in tape waters of the south Pannonian basin (Serbia) and arsenic risk assessment
Petar Papić, Marina Ćuk, Maja Todorović, Jana Stojković, Bojan Hajdin, Nebojša Atanacković, Dušan Polomčić (2012)... this study, and consequently with higher estimated toxic and carcinogenic risk should be con- nected to the new treatment for water supply. The minimum As water gave HQ and R values of 0.29 and 0.13 per 1,000 persons, respectively, and the maximum As water resulted in HQ and R of 5.72 and 2.6 per 1,000 ...
... existence of toxic risk. Futhermore, in the study area the minimum As water gave HQ and R values of 0.29 and 0.13 per 1,000 persons, respectively, and the maximum As water resulted in HQ and R of 5.72 and 2.6 per 1,000 persons, and this should indicate the importance of developing a regional water sup- ply system ...
... Austria and Slovenia to the Carpathian Mountains in Romania. In the south, the basin is bordered by the North Dinarides in Croatia, Bosnia and Herzegovina, and Serbia, and in the north by the Tatras in Slovakia. The Danube River is also the western boundary toward Croatia, while to the north and northeast ...Petar Papić, Marina Ćuk, Maja Todorović, Jana Stojković, Bojan Hajdin, Nebojša Atanacković, Dušan Polomčić. "Arsenic in tape waters of the south Pannonian basin (Serbia) and arsenic risk assessment" in Polish Journal of Enivronmental Studies 21 no. 6, Olsztyn, Poland : Polish Journal of Enivronmental Studies (2012): 1783-1790
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Investigation of Co0.9Ho0.1MoO4 Nanopowders Obtained by Glycine Nitrate Procedure
Milena Rosić, Maja Milošević, Maria Čebela, Vladimir Dodevski, Vesna Lojpur, Radomir Ljupković, Aleksandra Zarubica (2023)... Technology and Metallurgy, Ss. Cyril and Methodius University in Skopje, R. N. Macedonia Iva Dimitrievska, MSc, Faculty of Technology and Metallurgy, Ss. Cyril and Methodius University in Skopje, R. N. Macedonia Marija Prosheva, MSc, Faculty of Technology and Metallurgy, Ss. Cyril and Methodius ...
... Sciences and Mathematics, Ss. Cyril and Methodius University in Skopje, R. N. Macedonia Prof. Dr. Viktor Stefov, Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Ss. Cyril and Methodius University in Skopje, R. N. Macedonia Prof. Dr. Blazo Boev, Faculty of Natural and Technical ...
... Natural Sciences and Mathematics, Ss. Cyril and Methodius University in Skopje, R. Macedonia Marinela Cvetanoska, MSc, Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Ss. Cyril and Methodius University in Skopje, R. Macedonia COORGANIZERS: Minstry of Education and Science of ...Milena Rosić, Maja Milošević, Maria Čebela, Vladimir Dodevski, Vesna Lojpur, Radomir Ljupković, Aleksandra Zarubica. "Investigation of Co0.9Ho0.1MoO4 Nanopowders Obtained by Glycine Nitrate Procedure" in Book of Abstracts / 26th Congress of SCTM with international participation, 20-23 September 2023, Ohrid, R. Macedonia, Skopje : Society of Chemists and Technologists of Macedonia (2023)
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Flyrock induced by blasting in surface mining
Milanka Negovanović, Lazar Kričak, Snežana Ignjatović, Stefan Milanović, Jovan Marković, Nikola Simić, Rade Šarac (2022)Miniranje predstavlja i dalje najefikasniji i najjeftiniji način eksploatacije velikih količina čvrstih mineralnih sirovina na površinskim kopovima. Energija eksplozije se koristi za fragmentaciju čvrste stenske mase do zahtevane granulacije. Pored pozitivnih efekata miniranja, postoje i određeni neželjeni efekti svakog procesa miniranja koji se mogu javiti, a to su: potresi tla, razletanje komada stene, vazdušni udari, otrovni i zagušljivi gasovi i prašina. Razletanje komada stene je nekontrolisano izbacivanje fragmenata odminirane stenske mase i predstavlja jedan od glavnih izvora materijalne štete ...Milanka Negovanović, Lazar Kričak, Snežana Ignjatović, Stefan Milanović, Jovan Marković, Nikola Simić, Rade Šarac. "Flyrock induced by blasting in surface mining" in Rudarski glasnik, Beograd : Rudarski institut (2022). https://doi.org/10.25075/BM.2022.05
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Selection of Artificial Lift Methods: A Brief Review and New Model Based on Fuzzy Logic
Miroslav Crnogorac, Miloš Tanasijević, Dušan Danilović, Vesna Karović Maričić, Branko Leković (2020)Artificial lift methods have applications in oil wells where oil production is no longer possible due to natural reservoir energy, so this necessary energy is added by introducing lift methods. In order to achieve optimum production, the selection of an artificial lift method is very important. This paper uses fuzzy logic as a mathematical and conceptual model for selection of the optimal artificial lift method. The outcome or IF-THEN rules, as the central part of the model, is based ...... match completely. Author Contributions: Conceptualization, M.T. and M.C.; methodology, M.T. and D.D.; supervision, V.K.M. and B.L.; validation, D.D. and V.K.M.; formal analysis and writing—original draft M.C. All authors have read and agreed to the published version of the manuscript. Funding: This ...
... 1988, Valentin and Hoffman created the OPUS Expert System program, which apart from the parameters of methods and characteristics of the well and reservoir, also takes into account economic aspects (costs) [7]. In 1994, Espin and a group of authors observed technical characteristics and then economic ...
... fluid and working conditions, as technical limitations of artificial lift methods. The expert reviews all the parameters and decides which is the best method [6,8,10,15]. The second group (II) is expert systems: these are programs that analyze all parameters, both technical and economic, and in the ...Miroslav Crnogorac, Miloš Tanasijević, Dušan Danilović, Vesna Karović Maričić, Branko Leković. "Selection of Artificial Lift Methods: A Brief Review and New Model Based on Fuzzy Logic" in Energies, MDPI AG (2020)
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A fuzzy-based decision support model for effectiveness evaluation - a case study of examination of bulldozers
Effectiveness evaluation is one of the basic components of engineering asset management and maintenance engineering in general. Effectiveness is an overall concept representing a measurement of quality of service level for the analyzed engineering system. This concept contains a series of partial indicators relating to time in operation and time for maintenance activities, as well as functional properties of the system. This article describes the analysis and structuring of partial indicators, as well as the development of a model ...Miloš Tanasijević, Predrag Jovančić, Dejan Ivezić, Uglješa Bugarić, Radiša Đurić. "A fuzzy-based decision support model for effectiveness evaluation - a case study of examination of bulldozers" in International Journal of Industrial Engineering: Theory, Applications and Practice (2019)
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Permanent GNSS monitoring of landslide Umka
Mileva Samardžić Petrović, Jovan Popović, Uroš Đurić, Biljana Abolmasov, Marko Pejić, Miloš Marjanović (2020)Клизиште Умка је једно од највећих насељених активних клизишта у Србији. Активност клизишта Умка се прати већ више од 85 година, различитим геотехничким и геодетским техникама. Од 2010. године, активност kлизишта се континуирано прати у реалном времену аутоматизованим перманентним системом за праћење базираним на Глобалним навигационим сателитским системима (ГНСС). Поред тога, од 2018. године активност клизишта се додатно прати кинематичким ГНСС одређивањем положаја скупа карактеристичних тачака као и применом UAV фотограметрије. Главни циљ овог рада је приказ резултата опажања три ...... technology for infrastructure facilities and terrain stability monitoring“, financed by Ministry of Education, Science and Technological Development of the Republic of Serbia, and the collaboration between University of Belgrade, Faculty of Mining and Geology and Faculty of Civil Engineering, Institute ...
... between Epoch 0 and Epoch 1 and between Epoch 0 and 96 PROCEEDINGS OF INTERNATIONAL CONFERENCE ON CONTEMPORARY THEORY AND PRACTICE IN CONSTRUCTION XIV PERMANENT GNSS MONITORING OF LANDSLIDE UMKA Epoch 2 were calculated. Subsequently, the magnitude of the displacement vector and the azimuth ...
... northwest and the vertical displacement was nearly -16 cm. Generally, both graphics indicate that the Umka landslide is moving continuously and significantly towards the northwest, i.e. towards the Sava river. The average annual 2D displacement was approximately 22 cm and 15 cm, for first and second ...Mileva Samardžić Petrović, Jovan Popović, Uroš Đurić, Biljana Abolmasov, Marko Pejić, Miloš Marjanović. "Permanent GNSS monitoring of landslide Umka" in International Conference on Contemporary Theory and Practice in Construction XIV Stepgrad, University of Banja Luka, Faculty of Architecture, Civil Engineering and Geodesy (2020). https://doi.org/10.7251/STP2014091S
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A Description of Morphological Features of Serbian: a Revision using Feature System Declaration
In this paper we discuss some well-known morphological descriptions used in various projects and applications (most notably MULTEXT-East and Unitex) and illustrate the encountered problems on Serbian. We have spotted four groups of problems: the lack of a value for an existing category, the lack of a category, the interdependence of values and categories lacking some description, and the lack of a support for some types of categories. At the same time, various descriptions often describe exactly the same ...... category for nouns are singular and plural (shared by all involved languages), and besides that dual (for Slovene and Czech) and count (for Bulgarian). This last value in Bulgarian is similar to ‘paukal’ in Serbian which is used with small numbers two, three and four. This value, however, does not ...
... gender masculine, and in the same time grammatical number singular and natural number plural. Natural gender and number, instead of grammatical gender and number are used for verbal forms sastali and su. To veče, petorica(fem/sing) džentlmenovih kolega sastali(masc/pl) su(pl) se već u osam časova ...
... notably MULTEXT-East and Unitex) and illustrate the encountered problems on Serbian. We have spotted four groups of problems: the lack of a value for an existing category, the lack of a category, the interdependence of values and categories lacking some description, and the lack of a support for some types ...Cvetana Krstev, Ranka Stanković, Vitas Duško. "A Description of Morphological Features of Serbian: a Revision using Feature System Declaration" in Proceedings of the 5th International Conference on Language Resources and Evaluation, LREC 2010, Valetta, Malta : European Language Resources Association (2010)
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Wordnet Development Using a Multifunctional Tool
Ivan Obradović, Ranka Stanković (2007)In this paper we present a multifunctional tool for manipulating heterogeneous language resources. The tool handles electronic dictionaries, wordnets and aligned texts, and provides for their synchronous use in various tasks. We focus here on the description of the possibilities this tool offers in the development of wordnets. Besides the wordnet module which enables parallel handling of two wordnets, other modules, such as the module for morphological dictionaries and the module for aligned texts, as well as available finite ...... regular expressions and inflectional and morphological finite state transducers (FSTs) to locate morphological, lexical and syntactic patterns, remove ambiguities, and tag simple and compound words in texts. The text parsing possibilities offered by regular expressions and FSTs proved also useful ...
... based on LADL format and supporting resources in Unicode has been developed in parallel, and is also available 6 . Since all three systems (Intex, Unitex, and NooJ) provide for processing of texts on basis of dictionaries, in combination with regular expressions and FSTs, and each of them has ...
... wordnets for Bulgarian, Greek, Romanian, Serbian and Turkish and expanding the Czech wordnet, followed an approach similar to EuroWordNet [13]. Namely, BalkaNet wordnets were also developed on basis of PWN and the top-ontology accepted in EuroWordNet, and aligned by using ILI. From a lexicographer’s ...Ivan Obradović, Ranka Stanković. "Wordnet Development Using a Multifunctional Tool" in Proceedings of the International Workshop Computer Aided Language Processing (CALP) '2007, Borovets, Bulgaria, September 2007, - (2007)
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Tectono-lithostratigraphic model of the Northern Banat Miocene sediments (Pannonian Basin, Serbia)
Dejan Radivojević, Ljupko Rundić (2017)... less present then Badenian one and could be found in a very limited area. Generally, these sediments are very thin and represented with siliciclastics and limestones. °e Pannonian, Pontian, Pliocene and Quaternary sediments belong to postrift stage in the broader sense and lays unconformably over the ...
... less present then Badenian one and could be found in a very limited area. Generally, these sediments are very thin and represented with siliciclastics and limestones. The Pannonian, Pontian, Pliocene and Quaternary sediments belong to postrift stage in the broader sense and lays unconformably over the ...
... occurred simultaneously throughout the area, and it is possible to speak only about synrift and postrift stage in the broader sense (MATENCO & RADIVOJEVIĆ, 2012). In the Serbian northeastern part of Pannonian Basin, sediments of the Lower and Middle (Badenian and Sarmatian) Miocene are assigned to synrift ...Dejan Radivojević, Ljupko Rundić. "Tectono-lithostratigraphic model of the Northern Banat Miocene sediments (Pannonian Basin, Serbia)" in 7th International Workshop: Neogene of Central and South-Eastern Europe, Velika, Croatia, maj 2017, Croatian Geological Society (2017)
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Serbian NER&Beyond: The Archaic and the Modern Intertwinned
U ovom radu predstavljamo srpski književni korpus koji se razvija pod okriljem COST Akcije „Distant Reading for European Literary History” CA16204. Koristeći ovaj korpus romana napisanih pre više od jednog veka, razvili smo i učinili javno dostupnim Sistem za prepoznavanje imenovanih entiteta (NER) obučen da prepozna 7 različitih tipova imenovanih entiteta, sa konvolucionom neuronskom mrežom (CNN), koja ima F1 rezultat od ≈91% na test skupu podataka. Ovaj model je dalje ocenjen na posebnom skupu podataka za evaluaciju. Završavamo poređenje ...... form of finite-state transducers (Vitas and Krstev, 2012), enabled the development of a comprehensive rule-based system for NER Srp- NER. This system presented by Krstev et al. (2014) targeted 11 classes of NEs: dates and time (moments and periods), money and mea- surement expressions, geopolitical ...
... names (co- untries, settlements, oronyms and hydronyms), and personal names (one or more last names with or without first names and nicknames). The system was developed to recognize NEs in 1253 newspapers and similar texts. It was manually evaluated on a sample of unseen newspaper texts. The overall ...
... were trained and evaluated (SpaCy and Stan- ford). As a support for the developed NER models, Šandrih et al. (2019) joined several existing tools and developed various new tools, combined into a web platform NER&Beyond.2 Although NER systems in general were de- veloped mostly for newspaper and similar te- ...Branislava Šandrih Todorović, Cvetana Krstev, Ranka Stanković, Milica Ikonić Nešić. "Serbian NER&Beyond: The Archaic and the Modern Intertwinned" in Proceedings of the Conference Recent Advances in Natural Language Processing - Deep Learning for Natural Language Processing Methods and Applications, INCOMA Ltd. Shoumen, BULGARIA (2021). https://doi.org/10.26615/978-954-452-072-4_141
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Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles
Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović (2013)Kinetika i mehanizam reakcija supstitucije između [Ru(trpi)(bpi)Cl]+ sa nukleofilima gvanozin-5′-monofosfatom, L-histidinom, tioureom i dimetilsulfoksidom proučavani su spektrofotometrijski u 0,1 M NaClO4 na 310 K. Red reaktivnosti za odabrane ligande je: tiourea > gvanozin-5′-monofosfat > L-histidin > DMSO. Ovaj red je povezan sa elektronskim, strukturnim i hemijskim karakteristikama kompleksa i nukleofila. Reakcija supstitucije sa tioureom je proučavana na tri različite temperature (288, 298 i 310 K). Negativna entropija aktivacije DS = potvrđuje asocijativni način aktivacije. Formiranje kompleksa [Ru(trpi)(bpi)H2O]2+ sa ligandima ...... ? and L-His or 50-GMP by potentiometric and spectrophoto- metric methods. The structures of [Ru(trpy)(bpy)Cl]? and nucleophiles are shown in Fig. 1. Results and discussion Kinetic studies Kinetics of the substitution reactions of [Ru(trpy)(bpy)Cl]? with nucleophiles Tu, L-His, DMSO, and 50-GMP ...
... by the values of the sample standard deviation S and the goodness of fit v2 (Pearson’s test). At rE = 0.1 mV (0.001 pH error) and rV = 0.005 cm3, the values of S in different sets of titrations were between 1.0 and 1.8, and v2 was between 11.0 and 13.0. The scatter of residuals (Eobs - Ecalc) versus ...
... N-bpy)2Cl2] and mer-[Ru(N,N,N- trpy)Cl3] [12, 13], aminocarboxylato complexes [Ru(N,- N,O,O-pdta)Cl2] (pdta = 1,2- propylenediaminetetraacetato) and [Ru(N,N,O,O,O-edta)Cl] (edta = ethylenediaminete- traacetato) [14, 15], dimethylsulfoxide complexes cis- and trans-[Ru(S-DMSO)4Cl2] [16–18], and arylazopyrdine ...Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović. "Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles" in Monatshefte für Chemie - Chemical Monthly, Springer Science and Business Media LLC (2013). https://doi.org/10.1007/s00706-013-1044-1
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Late and post-collisional tectonic evolution of the Adria-Europe suture in the Vardar Zone
The Vardar Zone is a product of the Triassic-Jurassic opening of the Neotethys, Jurassic obduction, Late Cretaceous/Paleogene consumption of the oceanic crust and continental collision. During the last process, the Eastern Vardar Zone was thrust over the Central and eventually both onto the Western Vardar Zone. The present paleomagnetic and structural study provided new results from the first two zones in the Belgrade area. The younger set of data, together with published ones from the third zone, provide firm ...Emő Márton, Marinko Toljić, Vesna Cvetkov. "Late and post-collisional tectonic evolution of the Adria-Europe suture in the Vardar Zone" in Journal of Geodynamics, Elsevier BV (2022). https://doi.org/10.1016/j.jog.2021.101880