Претрага
126 items
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Analysis Of the Process Of Carbon Capture Utilization And Storage In Underground Reservoirs
John Nyame (2024)The importance of mitigating the effects of global climate change has necessitated an in-depth exploration of innovative strategies to reduce carbon dioxide (CO2) emissions. Among these strategies, Carbon Capture, Utilization, and Storage (CCUS) has emerged as a promising and transformative solution. This master thesis delves into the diverse realm of CCUS processes, aiming to unravel the positives challenges, and opportunities within this dynamic field. The analysis begins with a systematic examination of carbon capture technologies, encompassing post-combustion, pre-combustion, and oxy-fuel combustion ...... reaction or combustion of air or oxygen with fuel and in some cases steam to produce a gas mainly of carbon monoxide and hydrogen, which is known as synthesis gas (syngas) or fuel gas. CO2 is then separated, usually by chemical absorption process resulting in a hydrogen-rich fuel that can be used in many ...
... settle to the bottom of the tank. The latter NH4CI can be recycled by thermal operations with calcium oxide or be used as a feedstock for the synthesis of ammonia and chlorine. The hydrate-forming method is another technique that is used for desalination, and it involves the formation of hydrates ...
... acrylates (10 Mt year), polycarbonates (4 Mt year), and alkylene carbonates (a few kT year!). It is also widely used as a feedstock in polymer synthesis, pharmaceuticals, fine chemicals, and inorganic chemicals such as melamine and urea resins [25]. In addition to EOR, utilizing CO2 as a technological ...John Nyame. Analysis Of the Process Of Carbon Capture Utilization And Storage In Underground Reservoirs, 2024
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Punctuated, episodic magmatism and mineralization of the Rogozna skarn-hosted Au-Zn-Pb-Cu deposits revealed through high-precision U-Pb zircon geochronology
The subvolcanic regions of magmatic centers are commonly associated with alteration, mineralization, and economic ore deposits, however the duration and frequency of mineralizing pulses within the overall lifespan of these centers can be poorly defined. Therefore, models for the formation of mineral systems require more highprecision geochronology data to refine their evolutionary models. Rogozna Mountain and its eponymous magmatic complex, located in SW Serbia, hosts multiple base metal deposits associated with variable rock types and structural expressions and serves as a natural laboratory to ...Skarnovska mineralizacija, Magmatsko-hidrothermalni sistemi, Subvulcanske intruzije, geohronologija na cirkonima, CA-ID-TIMSSean P. Gaynor, Milorad D. Antić, Vladica Cvetković, Kristina Šarić, Urs Schaltegger. "Punctuated, episodic magmatism and mineralization of the Rogozna skarn-hosted Au-Zn-Pb-Cu deposits revealed through high-precision U-Pb zircon geochronology" in Ore Geology Reviews, Elsevier (2023). https://doi.org/https://doi.org/10.1016/j.oregeorev.2023.105775
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A hydrogeological model of the open-cast mine Tamnava - West Field (Kolubara Coal Basin, Serbia)
... aquifers in the study area, their interactions, and groundwater flow conditions. Based on geologic and hydrogeologic exploration, and analysis and synthesis of the collected data, the paper describes hydrogeologic modeling of the open-cast mine Tamnava – West Field. The software used in the research ...Jelena Ratković, Dušan Polomčić, Dragoljub Bajić, Bojan Hajdin. "A hydrogeological model of the open-cast mine Tamnava - West Field (Kolubara Coal Basin, Serbia)" in Underground Mining Engineering no. 29, Belgrade : University of Belgrade - Faculty of mining and geology (2016): 43-54
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Life Cycle Assessment of Individual Wood Biomass Heating Systems in Households
The use of solid fuels (wood biomass and coal) for heating of households continues to be common practice within European countries. Solid fuel combustion in households contributes more than 46% to total emissions of fine particulate matter. In this study, a life-cycle assessment (LCA) of firewood-based and pellet-based heating systems is performed. These two systems represent two different types of individual wood biomass heating systems. In the case of the firewood-based heating systems, it is analyzed a typical stove ...... com/legacy/download/SimaPro8Tutorial.pdf (accessed 20 Sept. 2020). [16] IPCC, Intergovernmental Panel on Climate Change, Climate change (2014). Synthesis Report. Contribution of Working Groups I, II and III to the Fifth Assessment Report of the IPCC, IPCC, Geneva, Switzerland.https://www.ipcc.ch/ ...Boban Pavlović, Dejan Ivezić, Marija Živković. "Life Cycle Assessment of Individual Wood Biomass Heating Systems in Households" in 5th International Scientific Conference ”Conference on Mechanical Engineering Technologies and Applications” COMETa2020, East Sarajevo, 2020, University of East Sarajevo, Faculty of Mechanical Engineering East Sarajevo (2020)
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The influence of alkyl polyglucosides (and highly ethoxylated alcohol boosters) on the phase behavior of a water/toluene/technical alkyl polyethoxylate microemulsion system
Marija Ilic, Franz-Hubert Haegel, Vesna Pavelkic, Dragan Zlatanovic, Snezana Nikolic-Mandic, Aleksandar Lolic, Zoran Nedic (2016)The influence of additives (alkyl polyglucoside, Glucopon 600 CS UP and alcohol ethoxylate C18E100) on the behavior of the water/toluene/Lutensol ON 50 (technical oxoalcohol, i-C10E5) microemulsion system as a function of temperature and composition has been investigated. The phase behavior of the microemulsions was determined by vertical sections through the Gibbs phase prism (fish-like phase diagrams). Alkyl polyglucoside shifts the one phase region to lower temperatures compared with water/toluene/Lutensol ON 50 mixtures. This is contrary to the expectation, considering ...микроемулзија, толуен, алкил полиглукозид, оксоалкохол етоксилат, појачивач ефикасности, „fish“ дијаграми... under project number 172051, D. Richter and J. Allgaier (JCNS-1), Forschungszentrum, Julich, for providing experimen- tal equipment and the synthesis of Cy+gEio. Lutensol ON 50 was a gift from BASF. Glucopon 600 CS UP was a gift from Cognis. M. Ilić further thanks DAAD (Germany) for a scholarship ...Marija Ilic, Franz-Hubert Haegel, Vesna Pavelkic, Dragan Zlatanovic, Snezana Nikolic-Mandic, Aleksandar Lolic, Zoran Nedic. "The influence of alkyl polyglucosides (and highly ethoxylated alcohol boosters) on the phase behavior of a water/toluene/technical alkyl polyethoxylate microemulsion system" in Chemical Industry and Chemical Engineering Quarterly, National Library of Serbia (2016). https://doi.org/ 10.2298/CICEQ141105015I
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Dehydroicetexanes in sediments and crude oils: Possible markers for Cupressoideae
Hans Peter Nytoft, Geir Kildahl-Andersen, Sofie Lindström, Frode Rise, Achim Bechtel, Danica Mitrović, Nataša Đoković, Dragana Životić, Ksenija A. Stojanović (2019)Two previously unidentified dehydroabietane isomers were isolated from Miocene Serbian lignite and Rhaetian (Late Triassic) coaly mudstones from South Sweden and characterized using NMRspectroscopy as cis- and trans-dehydroicetexane. Both have a 9(10?20)-abeo-abietane or icetexane skeleton, consisting of a 6-7-6 tricyclic framework with seven carbons in ring B instead of the usual six in common diterpanes of the abietane-type. Dehydroicetexanes can be detected using GC-MS-MS in m/z 270?146 chromatograms without interference from dehydroabietane or other isomers. Dehydroicetexanes are often abundant ...Hans Peter Nytoft, Geir Kildahl-Andersen, Sofie Lindström, Frode Rise, Achim Bechtel, Danica Mitrović, Nataša Đoković, Dragana Životić, Ksenija A. Stojanović. "Dehydroicetexanes in sediments and crude oils: Possible markers for Cupressoideae" in Organic Geochemistry, Elsevier BV (2019). https://doi.org/10.1016/j.orggeochem.2019.01.001
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Srbija u OneGeology Europe
Геолошки завод Србије као носилац Пројекта ОneGeologyEurope заједно са Рударско геолошким факултетом и Министарством за природне ресурсе, рударство и просторно планирање су се укључили у међународни Пројекат OneGeology Europe у мају 2013. године у већ поодмаклој фази израде Пројекта. До краја 2013. године испунили су завршене активности које треба да доведу до пуноправног укључења у Пројекат чиме је Република Србија нашла своје место на Геолошкој карти Европе 1:1М. Геолошка карта Србије 1:1М представља компилациону односно поједностављену верзију ОГК 1:500 ...... translation and publishing of web services. The final map is a simplified version of OGK 1:500,000, which is basically a compilation, made successive synthesis of data started at maps 1:25000, after 1:50 000 and 1:100 000 to map 1:200 000 (various authors from 1950 to 1968). Relevant criteria were used ...
... translation and publishing of web services. The final map is a simplified version of OGK 1:500,000, which is basically a compilation, made successive synthesis of data started at maps 1:25000, after 1:50 000 and 1:100 000 to map 1:200 000 (various authors from 1950 to 1968). Relevant criteria were used to ...Danka Blagojević, Ranka Stanković, Petar Stejić, Velizar Nikolić. "Srbija u OneGeology Europe" in Zapisnici Srpskog geološkog društva za 2013. godinu, Beograd : Srpsko geološko društvo (2014)
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Structural dissymmetrization of optically anisotropic Grs64±1Adr36±1Sps2 grandite from Meka Presedla (Kopaonik Mt., Serbia)
In this paper, grandite core with Grs64±1Adr36±1Sps2composition was crystallographically studied. This core represents zone A of the macroscopically visiblefive A–E zones of the optically anisotropic Grs58–64 Adr36–42Sps2 grandite. The applied procedure includes the detailed analysis of the powder diffraction patterns, and the Rietveld refinements of the crystal structures in a series of 18 space groups and two mixtures, which were followed by the comparative analysis of the R-values, site occupancy factors, and the bond lengths and angles. Synthesis of all ...Pavle Tančić, Aleksandar Kremenović, Predrag Vulić. "Structural dissymmetrization of optically anisotropic Grs64±1Adr36±1Sps2 grandite from Meka Presedla (Kopaonik Mt., Serbia)" in Powder Diffraction, Cambridge University Press (CUP) (2019). https://doi.org/10.1017/S0885715619000897
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Српски језик у дигиталном добу -- The Serbian Language in the Digital Age
Duško Vitas, Ljubomir Popović, Cvetana Krstev, Ivan Obradović, Gordana Pavlović-Lažetić, Mladen Stanojević (2012)... language learning ‚ information retrieval ‚ information extraction ‚ text summarisation ‚ question answering ‚ speech recognition ‚ speech synthesis Language technology is an established area of research with an extensive set of introductory literature. e in- terested reader is referred to the ...
... determines which words are actually spoken in a given sequence of sounds uttered by a user. 62 Speech Input Signal Processing Speech Output Speech Synthesis Phonetic Lookup & Intonation Planning Natural Language Understanding & Dialogue Recognition 9: Speech-based dialogue system 2. Natural language ...
... cording to the system in question. 3. Dialogue management determines which action to take given the user input and system functionality. 4. Speech synthesis (text-to-speech or TTS) trans- forms the system’s reply into sounds for the user. One of the major challenges of ASR systems is to ac- curately recognise ...Duško Vitas, Ljubomir Popović, Cvetana Krstev, Ivan Obradović, Gordana Pavlović-Lažetić, Mladen Stanojević. "Српски језик у дигиталном добу -- The Serbian Language in the Digital Age" in META-NET White Paper Series, G. Rehm, H. Uszkoreit (eds.), Springer (2012)
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A Lexical Approach to Acronyms and their Definitions
In this paper we present a comprehensive approach to acronyms for Natural-Language Processing (NLP) of Serbian texts. The proposed procedure includes extraction of acronyms and their definitions that are usual Multi-Word Units (MWUs), shallow parsing of MWUs that enables MWU lemmatization and production of entries in morphological electronic dictionaries, both for MWU and acronyms, that are provided with grammatical, syntactic, semantic and domain information. This approach enables representation that reflects complex relations between acronyms and their definitions.... mining and ontologies in biomedicine: mak- ing sense of raw text. Briefings in bioinformatics, 6(3):239–251. Taylor, Paul, 2009. Text-to-speech synthesis. Cambridge University Press. Tsimpouris, C., K. Sgarbas, and S. Panagiotopoulou, 2014. Acronym identification in Greek legal texts. Literary and ...Cvetana Krstev, Duško Vitas, Ranka Stanković. "A Lexical Approach to Acronyms and their Definitions" in Proceedings of the 7th Language & Technology Conference, November 27-29, 2015, Poznań, Poland, Springer (2015)
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Overcoming the Low Oral Bioavailability of Deuterated Pyrazoloquinolinone Ligand DK-I-60-3 by Nanonization: A Knowledge-Based Approach
Jelena R. Mitrović , Branka Divović-Matović, Daniel E. Knutson, Jelena B. Ðoković, Aleksandar Kremenović, Vladimir D. Dobričić, Danijela V. Randjelović, Ivana Pantelić, James M. Cook, Miroslav M. Savić, Snežana D. Savić (2021)Poor water solubility of new chemical entities is considered as one of the main obstacles in drug development, as it usually leads to low bioavailability after administration. To overcome these problems, the selection of the appropriate formulation technology needs to be based on the physicochemical properties of the drug and introduced in the early stages of drug research. One example of the new potential drug substance with poor solubility is DK-I-60-3, deuterated pyrazoloquinolinone, designed for the treatment of various neuropsychiatric ...... with improved metabolic stability to retard O-demethylation. Deuteration of both C4′ and C7′ methoxy groups in the parent molecule resulted in the synthesis of the ligand DK-I-60-3 (7-Methoxy-d3-2-(4-methoxy- d3-phenyl)-2,5-dihydro-3Hpyrazolo[4,3-c]quinolin-3-one). Extensive research published in Knutson ...
... ; Kodali, R.; Divović, B.; Treven, M.; Stephen, M.R.; Zahn, N.M.; Dobričić, V.; Huber, A.T.; Meirelles, M.A.; Verma, R.S.; et al. Design and synthesis of novel deuterated ligands functionally selective for the γ-aminobutyric acid type A receptor (GABAAR) α6 subtype with improved metabolic stability ...Jelena R. Mitrović , Branka Divović-Matović, Daniel E. Knutson, Jelena B. Ðoković, Aleksandar Kremenović, Vladimir D. Dobričić, Danijela V. Randjelović, Ivana Pantelić, James M. Cook, Miroslav M. Savić, Snežana D. Savić. "Overcoming the Low Oral Bioavailability of Deuterated Pyrazoloquinolinone Ligand DK-I-60-3 by Nanonization: A Knowledge-Based Approach" in Pharmaceutics, MDPI, Basel, Switzerland (2021). https://doi.org/10.3390/pharmaceutics13081188
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Comprehensive Profiling of Microbiologically Induced CaCO3 Precipitation by Ureolytic Bacillus Isolates from Alkaline Soils
Olja Šovljanski, Lato Pezo, Jovana Stanojev, Branimir Bajac, Sabina Kovač, Elvira Tóth, Ivan Ristić, Ana Tomić, Aleksandra Ranitović, Dragoljub Cvetković, Siniša Markov (2021)MICP process, kinetic study, calcite, vaterite, MALDI-TOF identification, Bacillus licheniformis, Sporosarcina pasteurii... prepared by carbonation. J. Mater. Sci. 2006, 41, 4663–4667. 57. Donnelly, F.C.; Purcell-Milton, F.; Framont, V.; Cleary, O.; Dunne, P.W.; Gunko, Y.K. Synthesis of CaCO3 nano- and micro-particles by dry ice carbonation. Chem. Commun. 2017, 53, 6657–6660. [CrossRef] [PubMed] 58. Qian, M.; Zuo, Y.; Chen, Z ...
... CaCO3 in aqueous solutions with extremely high concentrations of NaCl. Crystals 2019, 9, 647. [CrossRef] 59. Tang, H.; Yu, J.; Zhao, X. Controlled synthesis of crystalline calcium carbonate aggregates with unusual morphologies involving the phase transformation from amorphous calcium carbonate. Mater. ...Olja Šovljanski, Lato Pezo, Jovana Stanojev, Branimir Bajac, Sabina Kovač, Elvira Tóth, Ivan Ristić, Ana Tomić, Aleksandra Ranitović, Dragoljub Cvetković, Siniša Markov. "Comprehensive Profiling of Microbiologically Induced CaCO3 Precipitation by Ureolytic Bacillus Isolates from Alkaline Soils" in Microorganisms, MDPI AG (2021). https://doi.org/10.3390/microorganisms9081691
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Freeze-dried nanocrystal dispersion of novel deuterated pyrazoloquinolinone ligand (DK-I-56-1): Process parameters and lyoprotectant selection through the stability study
Jelena R. Mitrović, Maja Bjelošević Žiberna, Aleksandar Vukadinović, Daniel E. Knutson, Dishary Sharmin, Aleksandar Kremenović, Pegi Ahlin Grabnar, Odon Planinšek, Dominique Lunter, James M. Cook, Miroslav M. Savić, Snežana D. Savić (2023)Recently, nanocrystal dispersions have been considered as a promising formulation strategy to improve the bioavailability of the deuterated pyrazoloquinolinone ligand DK-I-56-1 (7‑methoxy-2-(4‑methoxy-d3-phenyl)-2,5-dihydro-3H-pyrazolo[4,3-c]quinolin-3-one). In the current study, the freeze-drying process (formulation and process parameters) was investigated to improve the storage stability of the previously developed formulation. Different combinations of lyoprotectant (sucrose or trehalose) and bulking agent (mannitol) were varied while formulations were freeze-dried under two conditions (primary drying at -10 or -45 °C). The obtained lyophilizates were characterized in terms ...... deuterated derivatives, DK-I-56-1 was selected as the lead ligand for future studies based on its good phar- macological profile and relative ease of synthesis (Knutson et al., 2018). Due to low solubility of DK-I-56-1 in water as well as in many commonly used oils, co-solvents, and organic solvents, ...
... Kodali, R., Divović, B., Treven, M., Stephen, M.R., Zahn, N.M., Dobričić, V., Huber, A.T., Meirelles, M.A., Verma, R.S., et al., 2018. Design and synthesis of novel deuterated ligands functionally selective for the y-aminobutyric acid type a receptor (GABAAR) o6 subtype with improved metabolic stability ...Jelena R. Mitrović, Maja Bjelošević Žiberna, Aleksandar Vukadinović, Daniel E. Knutson, Dishary Sharmin, Aleksandar Kremenović, Pegi Ahlin Grabnar, Odon Planinšek, Dominique Lunter, James M. Cook, Miroslav M. Savić, Snežana D. Savić. "Freeze-dried nanocrystal dispersion of novel deuterated pyrazoloquinolinone ligand (DK-I-56-1): Process parameters and lyoprotectant selection through the stability study" in European Journal of Pharmaceutical Sciences, Elsevier BV (2023). https://doi.org/10.1016/j.ejps.2023.106557
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Integrative GHG Assessment in Oil and Gas Industry
Reducing greenhouse gas emissions is one of the main targets of national strategies in European countries. As a main contributor to emissions, the energy sector is recognized as the most promising to apply measures and actions aimed to decrease GHG emissions. The Oil and Gas industry as a significant contributor to global greenhouse gas emissions is facing a growing need for estimating, mitigating, and reducing the impact of their operations on the atmosphere to stay competitive in a newly ...... ads&mtm_medium-=google- ads&mtm_content=cen&gclidEAlalQobChMliq p_5Gs_glV_4loCR2- SQKVEAAYAIAAEgLnnvD_BwE [pristupljeno 10.02.2023| 5] AR Synthesis Report: Climate Change 2023, in Proc. 60h 4ssessment Report during the Panel's 58th Session, Interlaken, Switzerland, 13-19 March 2023. https://www ...Aleksandar Mirković, Marija Živković, Stevan Đenadić, Darja Lubarda, Chinedu Anyanwa. "Integrative GHG Assessment in Oil and Gas Industry" in Energija, ekonomija, ekologija (2023). https://doi.org/10.46793/EEE23-1.51M
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Geochemical evaluation of dolostone deposits in Montenegro: Implications for potential industrial applications
Darko Bozovic, Vladimir Simic, Dragan Radulovic, Slobodan Radusinovic, Vesna Matovic, Anja Terzic (2024)This study presents a unique model for assessing the dependability of continuous parts of combined systems in open-pit mining through the application of fuzzy logic. Continuous sub-systems as part of the combined system of coal exploitation in surface mines have the basic function of ensuring safe operation, high capacity with high reliability, and low costs. These subsystems are usually part of the thermal power plant’s coal supply system and ensure stable fuel supply. The model integrates various independent partial ...примарне сировине, минералогија, физичко-механичка својства, технолошка својства, наука о материјалимаDarko Bozovic, Vladimir Simic, Dragan Radulovic, Slobodan Radusinovic, Vesna Matovic, Anja Terzic. "Geochemical evaluation of dolostone deposits in Montenegro: Implications for potential industrial applications" in Science of Sintering, Bor, August 2024, National Library of Serbia (2024). https://doi.org/10.2298/SOS240701029B
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Application of geophysical and multispectral imagery data for predictive mapping of a complex geo-tectonic unit: a case study of the East Vardar Ophiolite Zone, North-Macedonia
... metamorphic rocks, which are typically the oldest units in the study area: Precambrian and Paleozoic metamorphites. To obtain a comprehensive synthesis of the geological evolution of the EVZ, it is recommended to refer to the work of Boev et al. (2018). To simplify the geological analysis and ...
... 000. Federal Geological Institute, Belgrade Boev B, Cvetković V, Prelević D, Šarić K, Boev I (2018) East Var- dar Ophiolites Revisited A Brief Synthesis Of Geology And Geochemical Data. Contrib Sec Nat Math Biotech Sci, Mac- edonian Academy of Sciences and Arts 39:51—68. https://doi. org/10. ...Filip Arnaut, Dragana Đurić, Uroš Đurić, Mileva Samardžić-Petrović, Igor Peshevski. "Application of geophysical and multispectral imagery data for predictive mapping of a complex geo-tectonic unit: a case study of the East Vardar Ophiolite Zone, North-Macedonia" in Earth Science Informatics, Springer Science and Business Media LLC (2024). https://doi.org/10.1007/s12145-024-01243-4
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Генеза хидротермалног Cu-Au система Чукару Пеки (Источна Србија)
Милош Велојић (2021)Главни циљ испитивања хидротермалног система Чукару Пеки је разумевање процеса који су довели до његовог настанка, а посебно еволуције рудоносних флуида из којих је настала рудна минерализација. Утврђено је да је овај систем настао у периоду пре 86,78 - 85,19 Ma из магматског интрузива који је био богат водом и имао висок оксидативни потенцијал. Током хлађења, из овог магматског интрузива су издвојени веома врели флуиди, који су имали температуре изнад 600°С и висок салинитет. У ...Борска металогенетска зона, Тимочки магматски комплекс, порфирска лежишта, високосулфидациона лежишта, флуидне инклузије, рудне парагенезе, геохронологија, хидротермалне алтерације, LA-ICP-MS... THE GENESIS OF HYDROTHERMAL Cu-Au SYSTEM ČUKARU PEKI (EASTERN SERBIA) Abstract: The main goal of thе reseаrch conducted on the hydrothermal system of Čukaru Peki is the understanding of processses which led to its formation, with an emphasis on the evolution of hydrothermal fluids which led ...
... g magmatic-hydrothermal systems. Geology, 39(8), 731-734. 144. Wilkinson, J.J., 2001. Fluid inclusions in hydrothermal ore deposits. Lithos, 55(1-4), 229-272. 145. Williams-Jones, A. E., & Heinrich, C. A., 2005. Vapor transport of metals and the formation of magmatic-hydrothermal ore deposits ...
... Steele-MacInnis, M., 2014. 13.5 — Fluid inclusions in hydrothermal ore deposits. Treatise on Geochemistry, Second Editionth edn. Elsevier, Oxford, 119-142. 19. Bogie, I., Lawless, J. V., Rychagov, S., & Belousov, V., 2005. Magmatic-related hydrothermal systems: Classification of the types of geothermal ...Милош Велојић. Генеза хидротермалног Cu-Au система Чукару Пеки (Источна Србија), Београд : [М. Велојић], 2021
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The external aggregation Newton's method for solving nonlinear equations and applications
Marija Paunović, Dejan Ćebić, Nebojša Ralević. "The external aggregation Newton's method for solving nonlinear equations and applications" in The University Thought - Publication in Natural Sciences, Centre for Evaluation in Education and Science (CEON/CEES) (2020). https://doi.org/10.5937/univtho10-24982
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Supstitucione reakcije Pd(II) kompleksa sa biološki važnim biomolekulima
Aleksandar M. Mijatović, Jovana Bogojeski. "Supstitucione reakcije Pd(II) kompleksa sa biološki važnim biomolekulima" in Hemijski pregled, Srpsko hemijsko društvo (2017)
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Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles
Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović (2013)Kinetika i mehanizam reakcija supstitucije između [Ru(trpi)(bpi)Cl]+ sa nukleofilima gvanozin-5′-monofosfatom, L-histidinom, tioureom i dimetilsulfoksidom proučavani su spektrofotometrijski u 0,1 M NaClO4 na 310 K. Red reaktivnosti za odabrane ligande je: tiourea > gvanozin-5′-monofosfat > L-histidin > DMSO. Ovaj red je povezan sa elektronskim, strukturnim i hemijskim karakteristikama kompleksa i nukleofila. Reakcija supstitucije sa tioureom je proučavana na tri različite temperature (288, 298 i 310 K). Negativna entropija aktivacije DS = potvrđuje asocijativni način aktivacije. Formiranje kompleksa [Ru(trpi)(bpi)H2O]2+ sa ligandima ...... pH, could contribute to a better understanding of some interactions in biological systems. Experimental RuCl3�xH2O, a starting salt for other synthesis, was pur- chased from Acros Organics. The ligands thiourea (Tu), dimethylsulfoxide (DMSO), guanosine-50-monophosphate sodium salt (50-GMP), 2, ...Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović. "Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles" in Monatshefte für Chemie - Chemical Monthly, Springer Science and Business Media LLC (2013). https://doi.org/10.1007/s00706-013-1044-1