Micro- to nanoscale textures of gold in arsenopyrite and scorodite from the As-Au-Bi assemblage of Drenjak locality (Serbia)
Објеката
- Тип
- Рад у часопису
- Верзија рада
- објављена верзија
- Језик
- енглески
- Креатор
- Ivana Jelić, Janez Zavašnik, Marina Lazarov, Alena Zdravković, Sabina Kovač, Jovica Stojanović, Aleksandar Pačevski
- Извор
- Ore Geology Reviews
- Издавач
- Elsevier BV
- Датум издавања
- 2023
- Сажетак
- Arsenopyrite and pyrite are important carriers of Au that is present in the form of microscopic and “invisible” gold. Such gold can be expected to be released upon the process of oxidation of these sulfides. In studied gold mineralization at Drenjak, related to the granitoids of the Oligocene-Miocene Kopaonik Ore District, the main arsenopyrite-pyrite-(bismuthinite) sulfide assemblage was formed in the quartz bodies and partly replaced by scorodite (FeAsO4·2H2O) and Bi-arsenate. With only up to 5 ppm of gold recorded by LA-ICP-MS, aforementioned sulfide minerals are here practically free from lattice-bound gold. Native gold is present in the mineralization, generally ranging in grain size from 20 µm down to the nanoparticles, as revealed by TEM. It is mainly hosted by arsenopyrite and scorodite. In arsenopyrite, gold is polycrystalline and consists of nanocrystallites 20–30 nm in size. It was deposited after arsenopyrite, healing its cavities and microcracks, often associated with native bismuth and bismuthinite. The abundance of gold and Bi minerals correlates with the presence of scorodite. Two types of gold are present in scorodite and Bi arsenate: i) prevailing relict Au grains retained after arsenopyrite oxidation, ii) colloidal-like gold co-precipitated with the arsenates. Based on our observations, we additionally present and discuss indications of low-temperature hydrothermal origin of scorodite, formerly known only as a weathering product.
- том
- 163
- почетак странице
- 105711
- број страница
- 14
- doi
- 10.1016/j.oregeorev.2023.105711
- issn
- 0169-1368
- Subject
- Economic Geology, Geochemistry and Petrology, Geology
- Шира категорија рада
- M20
- Ужа категорија рада
- М21
- Је дио
- 451-03-47/2023-01/200126
- Права
- Отворени приступ
- Лиценца
- Creative Commons – Attribution-NonComercial-No Derivative Works 4.0 International
- Формат
- Медија
2023_OreGeolReviews.pdf
Ivana Jelić, Janez Zavašnik, Marina Lazarov, Alena Zdravković, Sabina Kovač, Jovica Stojanović, Aleksandar Pačevski. "Micro- to nanoscale textures of gold in arsenopyrite and scorodite from the As-Au-Bi assemblage of Drenjak locality (Serbia)" in Ore Geology Reviews, Elsevier BV (2023). https://doi.org/10.1016/j.oregeorev.2023.105711
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