Surface functional groups and degree of carbonization of selected chars from different processes and feedstock
Објеката
- Тип
- Рад у часопису
- Верзија рада
- објављена верзија
- Језик
- енглески
- Креатор
- Marija Ilić, Franz-Hubert Haegel, Aleksandar Lolić, Zoran Nedić, Tomislav Tosti, Ivana Sredović Ignjatović, Andreas Linden, Nicolai D. Jablonowski, Heinrich Hartmann
- Извор
- PLOS ONE
- Датум издавања
- 2022
- Сажетак
- The knowledge ofthe structural and chemical properties of biochars is decisive for their application as technical products. For this reason, methods for the characterization of biochars that are generally applicable and allow quality control are highly desired. Several methods that have shown potential in other studies were used to investigate two activated carbons and seven biochars from different processes and feedstock. The chars were chosen to cover a wide range of chemical composition and structural properties as a hardness test for the analytical methods used in this study. Specific problems connected with the pretreatment of samples and drawbacks of some methods for some types of chars could be identified in an integrated consideration of the results from different methods. None of the spectroscopic methods was found to be suitable for the quality control of all types of chars. The most valuable results were obtained by chemical analysis that, however, required the complete determination of the main elements, including that of oxygen, and of inorganic components for adequate results. The combination of X-ray photoelectron spectroscopy (XPS) and FT-IR spectroscopy allows a rough characterization of surface functional groups, but cannolt discriminate aliphatic and aromatic OH groups. FT-IR might be a suitable method for the quality control of biochars made at lower temperature. The results of Raman spectroscopy did not well correlate with the amount of sp? hybridized carbon determined by XPS. A better correlation of XPS data was found with the electrical polarization determined by the method of spectral induced polarization that was used for the first time in conjunction with extensive analytical characterization.
- том
- 17
- Број
- 11
- doi
- 10.1371/journal.pone.0277365
- issn
- 1932-6203
- Subject
- Biougalj, različiti procesi dobijanja, različite sirovine, površinski aktivne grupe, x-ray, FT-IR,XPS
- Biochar, different production processes, different feedstock, surface functional groups, X-ray, FT-IR, XPS.
- Шира категорија рада
- M20
- Ужа категорија рада
- М22
- Је дио
- 172051 OI
- Права
- Отворени приступ
- Лиценца
- All rights reserved
- Формат
- Медија
Biochar-2022.pdf
Marija Ilić, Franz-Hubert Haegel, Aleksandar Lolić, Zoran Nedić, Tomislav Tosti, Ivana Sredović Ignjatović, Andreas Linden, Nicolai D. Jablonowski, Heinrich Hartmann. "Surface functional groups and degree of carbonization of selected chars from different processes and feedstock" in PLOS ONE (2022). https://doi.org/10.1371/journal.pone.0277365
This item was submitted on 29. новембар 2023. by [anonymous user] using the form “Рад у часопису” on the site “Радови”: https://dr.rgf.bg.ac.rs/s/repo
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